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^{1     NOTE: all WHMIS required information is included.  It is located in appropriate sections based on the ANSI Z400.1-1993 format.}

4. FIRST-AID MEASURES

This product is a gas; therefore, exposure via ingestion, ingestion, skin contact, or eye contact would be unlikely. Should exposure via inhalation occur, remove victims to fresh air, as quickly as possible. Trained personnel should administer supplemental oxygen and/or cardio-pulmonary resuscitation, if necessary. Only trained personnel should administer supplemental oxygen.

In case of frostbite, place the frostbitten part in warm water. If warm water is not available, or impractical to use, wrap the affected parts gently in blankets.

If exposure causes obvious distress, victim(s) and rescuers must be taken for medical attention. Take copy of label and MSDS to physician or health professional with victim.

5. FIRE-FIGHTING MEASURES

FLASH POINT, Degree C (method): Not applicable.

NFPA RANKING - HEALTH=1, FLAMMABILITY=0, REACTIVITY=0, OTHER=0

AUTOIGNITION TEMPERATURE, Degree C: Not applicable.
FLAMMABLE LIMITS (in air by volume, %):   Lower (LEL): Not applicable.
                                                                             Upper (UEL): Not applicable.

FIRE EXTINGUISHING MATERIALS: None.  This product is a fire extinguishing agent.

UNUSUAL FIRE AND EXPLOSION HAZARDS:  When involved in a fire, this cylinder under may rupture violently, causing a high pressure release of gases.

     Explosion Sensitivity to Mechanical Impact: Not sensitive.
     Explosion Sensitivity to Static Discharge: Not sensitive.

SPECIAL FIRE-FIGHTING PROCEDURES: Keep unused cylinders cool using a water spray.   Structural fire fighters must wear Self-Contained Breathing Apparatus and full protective equipment.

6. ACCIDENTAL RELEASE MEASURES

SPILL AND LEAK RESPONSE:  Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a release, clear the affected area, protect people, and respond with trained personnel. For uncontrolled releases, respond wearing Self-Contained Breathing Apparatus. Monitor the surrounding area for oxygen content. The atmosphere must have at least 19.5 percent oxygen before personnel can be allowed in the area without Self-Contained Breathing Apparatus. Ventilate the affected area.

7. HANDLING and STORAGE

WORK PRACTICES AND HYGIENE PRACTICES: Avoid getting chemicals ON YOU or IN YOU. Wash hands after handling chemicals. Do not eat or drink while handling chemicals. Be aware of any signs of dizziness or fatigue; exposures to fatal concentrations of this product could occur without any significant warning symptoms.

STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely. Keep cylinders in dry, well-ventilated areas which are away from sources of heat. Keep cylinders secure.

PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out safely. Always use this product in areas where adequate ventilation is provided. Decontaminate equipment using soapy water before maintenance begins. Collect all rinsates and dispose of according to applicable Federal, State, or local procedures.

8. EXPOSURE CONTROLS - PERSONAL PROTECTION

VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Use a mechanical fan or vent area to outside.
RESPIRATORY PROTECTION: Use supplied air respiratory protection if oxygen levels are below 19.5%.
EYE PROTECTION: Safety glasses.
HAND PROTECTION: None normally required.
BODY PROTECTION: Use body protection appropriate for task.
 

9. PHYSICAL and CHEMICAL PROPERTIES

10. STABILITY and REACTIVITY

STABILITY: Stable.
DECOMPOSITION PRODUCTS: Not applicable.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Upon contact with moisture, carbon dioxide can form carbonic acid.  Carbon dioxide is also incompatible with chemically active metals, such as sodium, potassium, and titanium.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Incompatible materials.

11. TOXICOLOGICAL INFORMATION

TOXICITY DATA: The following data is available for components of this produict greater than 1 percent by weight in concentration.

Carbon Dioxide:  This gas is a simple asphyxiant with physiological effects at high concentration.

TCLo(inhalation, rat) = 6 pph/24 hours; reproductive and teratogenic effects
LCLo(inhalation, human) = 9 pph/5 minutes
LCLo(inhalation, mammal) = 90,000 ppm/5 minutes

SUSPECTED CANCER AGENT: This product's ingredients are not found on the following lists: FEDERAL OSHA Z LIST, NTP, CAL/OSHA., IARC.

IRRITANCY OF PRODUCT: This product may cause mild skin and moderate eye irritancy.

SENSITIZATION TO THE PRODUCT: This product is not known to cause sensitization.

A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive process.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Contact with this product may aggravate pre-existing respiratory conditions.

RECOMMENDATIONS TO PHYSICIANS: Treat patient symptoms. Administer oxygen, as necessary.

12. ECOLOGICAL INFORMATION

ENVIRONMENTAL STABILITY: No adverse environmental consequences are expected.  All gases in this mixture occur naturally in the environment.  The gas will dissipate rapidly in well ventilated areas.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: None currently known.
EFFECT OF CHEMICAL ON AQUATIC LIFE: Not expected to harm aquatic life.

13. DISPOSAL CONSIDERATIONS

PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and local regulations.  This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.  Residue from fires extinguished with this material may be hazardous.
EPA WASTE NUMBER: Not applicable.

14. TRANSPORTATION INFORMATION

THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION. 

Note:  Fire extinguishers fall under the exception category for labeling under 49 CFG 173.309.  The "Non-Flammable Gas" label would not be added, except if the cylinder is offered for shipment by air.

MARINE POLLUTANT:  Not applicable.

THIS MATERIAL IS HAZARDOUS AS DEFINED BY TRANSPORT CANADA "TRANSPORTATION OF DANGEROUS GOODS" REGULATIONS.  See above information.

15. REGULATORY INFORMATION

SARA REPORTING REQUIREMENTS: Carbon Dioxide is not subject to the reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act.

SARA Threshold Planning Quantity: Not applicable.

TSCA INVENTORY STATUS: Carbon Dioxide is listed on the TSCA Inventory.

CERCLA REPORTABLE QUANTITY (RQ): Not applicable.

OTHER FEDERAL REGULATIONS: Not applicable.

STATE REGULATORY INFORMATION: Chemicals in this product are covered under specific State regulations, as denoted below:
 

CALIFORNIA PROPOSITION 65: Carbon dioxide is not listed on the California Proposition 65 lists.

LABELING (Precautionary Statements): WARNING! Liquefied gas under pressure. May cause frostbite burns. Exposure may cause headaches, dizziness, eye irritation. Use only in well-ventilated area. Store in a cool, dry location.

TARGET ORGANS: Respiratory system, skin, eyes.

WHMIS SYMBOLS:

16. OTHER INFORMATION

DEFINITIONS OF TERMS

A large number of abbreviations and acronyms appear on an MSDS. Some of these which are commonly used include the following: